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Cyclic Homo- and Heterohalogen Di-λ3-diarylhalonium Structures
(Journal of the American Chemical Society 2023, 145 (25), 13796–13804, 2023-06-28)In the context of the ever-growing interest in the cyclic diaryliodonium salts, this work presents synthetic design principles for a new family of structures with two hypervalent halogens in the ring. ... -
Cyclic Homo- and Heterohalogen Di-λ3-diarylhalonium Structures
(Journal of the American Chemical Society, 2023-06-13)In the context of the ever-growing interest in thecyclic diaryliodonium salts, this work presents synthetic designprinciples for a new family of structures with two hypervalenthalogens in the ring. The ... -
Exploring Structure–Activity Relationships in Photodynamic Therapy Anticancer Agents Based on Ir(III)-COUPY Conjugates
(Journal of Medicinal Chemistry 2023, 66 (12), 2023-06-22)Photodynamic therapy holds great promise as a non-invasive anticancer tool against drug-resistant cancers. However, highly effective, non-toxic, and reliable photosensitizers with operability under ... -
High photostability in nonconventional coumarins with far-red/NIR emission through azetidinyl substitution
(Journal of Organic Chemistry. Vol.83, n.19 (2018), p.11519-11531, 2018-08)Replacement of electron-donating N,N-dialkyl groups with three- or four-membered cyclic amines (e.g., aziridine and azetidine, respectively) has been described as a promising approach to improve some ... -
Mitochondria-Targeted COUPY Photocages: Synthesis and Visible-Light Photoactivation in Living Cells
(The Journal of Organic Chemistry 2023, 88, 7128-7140, 2023-06-02)Releasing bioactive molecules in specific subcellular locations from the corresponding caged precursors offers great potential in photopharmacology, especially when using biologically compatible visible ...